• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Process for monitoring anaerobic digesters, which makes use of a device comprising a microbial combustión cell (1) linked to an anaerobic digester (2) through at least a first conduit (3) and a second conduit (4), a voltmeter (13) that determines the difference of electric potential created inside the microbial combustión cell (1), and a control unit (14) that receives the measurements determined by the voltmeter (13). The anode (7) of the microbial combustión cell (1) is fed by a continuous flow comprising a mixture of effluent and biomass from the interior of the anaerobic digester (2), which allows a precise and continuous monitoring of the digestion process which is carried out inside said anaerobic digester (2). (Machine-translation by Google Translate, not legally binding)
    公开号:ES2638239A1
    申请号:ES201630320
    申请日:2016-03-18
    公开日:2017-10-19
    发明作者:Fernando GONZÁLEZ FERMOSO；Rafael Borja Padilla；Pablo María ABANS CARRASCO；Antonio SERRANO MORAL；Antonia Mercedes JIMENEZ RODRÍGUEZ
    申请人:Consejo Superior de Investigaciones Cientificas CSIC；Universidad Pablo de Olavide；
    IPC主号:
    专利说明:

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    PROCEDURE FOR MONITORING OF DIGESTORS ANAEROBIOS
    DESCRIPTION
    OBJECT OF THE INVENTION
    The present invention falls within the technical field of biological wastewater treatment, as well as that of microbial combustion cells, and refers in particular to a procedure for monitoring and controlling the risk factors that affect the process of Anaerobic digestion performed in reactors or digesters, said procedure being based on a microbial combustion cell attached and connected to an anaerobic digester, which allows the microbial activity present in the reactor to be related to the generation of an electrical potential.
    BACKGROUND OF THE INVENTION
    Anaerobic digestion is a technique for the treatment of organic waste through the action of microorganisms that, under anaerobic conditions, break down this organic matter. This process generates various gases, among which carbon dioxide (CO2) and methane (CH4) stand out.
    Anaerobic digestion processes usually comprise four fundamental and successive stages:
    - Hydrolysis, in which the size of the organic polymers that make up the biomass is reduced to facilitate access to them by microorganisms, giving rise to sugars, amino acids and simple fatty acids.
    - Acidogenesis, which results from the breakdown of the remaining components by fermentative bacteria resulting in volatile fatty acids, ammonia, carbon dioxide, sulfhydric acid and other by-products.
    - Acetogenesis in which the molecules from acidogenesis are digested by bacteria producing acetates, to produce mainly acetic acid, carbon dioxide and hydrogen.
    - Methanogenesis, in which methane-producing bacteria use the
    intermediate products of the previous stages to convert them into methane, carbon dioxide and water, the first two being the main components of the biogas emitted by the system. Methanogenesis occurs at pH values between 6.5 and 8.
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    In the so-called biodigesters or digesters of organic waste, this release of gases is used to be subsequently used as fuel. In its simplest form, biodigesters comprise a closed, airtight and impermeable container called a reactor, into which the organic material is deposited with a certain water dilution.
    Anaerobic digestion is a very delicate biological process due to the high number of factors that affect the activity of microorganisms and that can cause temporary or total system failures. For the recovery of the operation of the 15 digesters it would be necessary to re-start them, which implies the need to stop the process for long periods of time, the inability to treat waste during such periods and, consequently, both high economic costs and possible environmental impacts and problems of operation in the plant derived from the accumulation of unstabilized waste.
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    Controlling each one of the risk factors individually is an expensive, technologically complicated option that requires a high degree of specialization of the plant operators, so that, at present, the digesters are monitored based on variations in the production of biogas or factors such as pH or the accumulation of acids. However, in the majority of cases the detection of faults in the digester by means of these methods is not immediate to the appearance of these problems, with which the system has already been seriously damaged, reaching critical and irreversible situations.
    30 The use of microbial combustion cells as biosensors to control the risk factors of the anaerobic waste digestion process is known in the state of the art. Said cells are fed with the final effluent of an upstream flow digester, having the consideration of an independent and post reactor system.
    This configuration implies that the bacterial populations of the digester and the combustion cell are not the same and, therefore, the response offered by the cell is not representative of the actual behavior of the digester. Furthermore, when using the effluent from upflow reactors it is very possible that the detection of problems in the bed 5 of the reactor is not automatic, so that a solution to the previously described problems is not provided.
    DESCRIPTION OF THE INVENTION
    The object of the invention consists in a method for monitoring the risk parameters of the anaerobic digestion process that occurs inside a digester, which makes use of a device comprising a microbial combustion cell attached to said digester and which It is linked to it through a recirculation system that allows the microbial activity present in the reactor to be related to the generation
    15 of an electric potential inside the cell of the device, said cell being further linked to a voltmeter that determines the electric potential inside said cell, and to a control unit that receives the measurements made in the voltmeter.
    20 The procedure is based on the determination of the electric potential of the microbial cell under stable conditions and the subsequent monitoring of said potential, so that at the moment when significant variations of potential are detected the control unit issues a warning of failure in the system before an irreversible destabilization of the system occurs.
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    The microbial combustion cell of the device used in the process is made up of a pair of first plates, preferably of polymethylmethacrylate, with a flow channel and separated by a cation exchange membrane that divides the cell into two compartments: anode and cathode.
    30
    In the part of the anode is the biomass responsible for the oxidation of organic matter from the reactor. This biomass of the anode is analogous to that existing inside said reactor, since as indicated above, the recirculation is carried out of the reactor content, which comprises both the effluent entering the said reactor.
    reactor as part of its biomass bed.
    In the cathode part there is a reduction of iron from a catholyte, preferably composed of a solution of 16,470 g / L Fe (III) [CN] 63- and a 0.02 M phosphate buffer.
    To each of the sides of the first polymethylmethacrylate plates of the cell are linked two other second plates, preferably of graphite, which act as electrodes.
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    All the elements of the microbial combustion cell are linked together by two additional third polymethyl methacrylate plates fixed by screws made of a non-conductive material, preferably plastic.
    The electrodes of the cell are connected to a voltmeter, preferably equipped with an internal resistance of around 1000Q, which closes the circuit and measures the potential difference between the electrodes of the circuit in real time, preferably in continuous.
    20 Said voltmeter is also linked to a control unit that receives the measurements determined in real time by the voltmeter and, in case of significant variations in the electrical potential of the interior of the microbial combustion cell, emits a warning signal intended for an operator responsible for the control of the anaerobic digester to initiate an actuation protocol that detects and solves the cause of said variation in the electrical potential before the total paralysis of the anaerobic digestion process.
    The characteristic that the bacterial population present in the microbial combustion cell of the device is analogous to that existing in the digester, allows the response offered to be fully representative in time and form of the digester's functioning. In addition, since the microbial population developed in the cell bioanode is constantly renewed with contributions of microorganisms from the digester, both the microbial cell and the digester function as a single system capable of adapting to changes in the microbial population without varying the precision from his
    functioning.
    In the same way, this recirculation of microorganisms allows that, at the time of the start-up of the device, the inoculation of biomass in the membrane of the 5 cell of the device is carried out autonomously, avoiding the extraction of part of a digestate from of anaerobic digestion for manual inoculation of the membrane as a previous step to its installation as it happens with other devices.
    This gives a great versatility to the device and to the procedure associated to the 10 allowing it to be installed in any reactor regardless of the waste being treated, since the microbial population of the cell that oxidizes the organic matter from the reactor is formed from the same microbial population existing in the reactor. Likewise, in case of any problem in the population of membrane microorganisms, the device is capable of self-repair through the constant supply of new microorganisms from the digester.
    The energetic and maintenance costs of the procedure are practically nil, there being only the costs derived from the need for a small volume of recirculation and the maintenance of the device at the same operating temperature 20 existing in the reactor. This monitoring procedure is possible in reactors of all types and the operation of its associated device is adaptable to both the operating conditions and the type of waste to be treated.
    DESCRIPTION OF THE DRAWINGS
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    To complement the description that is being made and in order to help a better understanding of the characteristics of the invention, according to a preferred example of practical realization of the same, a set of drawings is accompanied as an integral part of said description. where, with an illustrative and non-limiting nature, the following has been represented:
    Figure 1.- Shows a schematic view of the disposition of the device associated with the monitoring procedure in an anaerobic digester.
    Figure 2.- Shows a schematic view of the device associated with the anaerobic digester monitoring procedure, in which its main constituent elements are appreciated.
    5 PREFERRED EMBODIMENT OF THE INVENTION
    Next, a detailed explanation of an example of preferred embodiment of the object of the present invention is provided with the aid of the aforementioned figures.
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    The device associated with the anaerobic digester monitoring procedure described comprises a microbial combustion cell (1) linked to an anaerobic digester (2) through a first duct (3) that carries part of both the effluent and the biomass contained inside the anaerobic digester (2) into the interior 15 of the microbial combustion cell (1) to proceed with a determination of the electrical potential created by the content of the anaerobic digester (2) and subsequently, through a second duct ( 4) return said content inside the anaerobic digester (2), as shown in the schematic view of Figure 1.
    The microbial combustion cell (1) in turn comprises a first pair of polymethylmethacrylate plates (5) separated from one another by means of a cation exchange membrane (6). Said cation exchange membrane (6) divides the inner cavity of the microbial combustion cell (1) into a first compartment, corresponding to the anode (7) and a second compartment, corresponding to the cathode (8).
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    As shown in Figure 2, the first conduit (3) introduces into the anode (7) of the microbial combustion cell (1) a continuous flow of the mixture of effluent and biomass from inside the anaerobic digester (2), which after being oxidized inside said microbial combustion cell (1) is recirculated into the anaerobic digester 30 (2) through the second duct (4).
    On the other hand, the cathode (8) is connected by a third conduit (9) and a fourth conduit (10) to a catholyte container (11). In the preferred embodiment described herein, the catholyte comprises a solution of 16,470 g / L of
    Fe (NI) [CN] 63- and a 0.02 M phosphate buffer, so that an iron reduction occurs inside the cathode (8).
    Thus, iron from the tank (11) is conducted through the third duct (9) 5 into the cathode (8) in the form of a ferric cation (Fe3 +), where it is reduced to ferrous (Fe2 +), said cation being Ferrous subsequently recirculated to the reservoir (11) by the fourth conduit (10).
    Each of the respective plates of the first pair of plates (5) of the microbial combustion cell (1) is linked to each of the plates of a second pair of graphite plates (12), said plates of the second pair acting of plates (12) as electrodes.
    A voltmeter (13) with a resistance of 1000Q and connected to each of the 15 graphite plates of the second pair of plates (12) closes the electrical circuit created in the microbial combustion cell (1) and measures in real time the potential difference of the electric circuit. It is envisioned that said voltmeter (13) is also linked to a control unit (14) that receives the measurements determined in real time by the voltmeter (13).
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    A third pair of polymethylmethacrylate plates (15) externally covers the microbial combustion cell (1), said third pair of plates (15) having holes made to allow the entry of the first conduit (3) and the second conduit (4) ) that link the microbial combustion cell (1) with the anaerobic digester (2).
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    The anaerobic digester monitoring procedure that makes use of the device thus described thus comprises the following phases:
    - entry into the anode (7) of the microbial combustion cell (1) of a continuous flow 30 comprising a mixture of effluent and biomass from inside the
    anaerobic digester (2) for oxidation,
    - entry into the cathode (8) of the microbial combustion cell (1) from the tank (11) of a catholyte for reduction,
    - measurement by voltmeter (13) of the potential difference created in
    inside the microbial combustion cell (1) due to oxidation and reduction reactions,
    - transmission of the potential difference measured by the voltmeter (13) to the control unit (14), and
    5 - exit of the anode (7) from the microbial combustion cell (1) of the mixture of
    Effluent and oxidized biomass through the second conduit (9) for its return to the interior of the anaerobic digester (2).
    In case of significant variations in the electric potential of the microbial combustion cell (1), the control unit (14) issues a warning signal for an operator responsible for the control of the anaerobic digester (2) to start an actuation protocol that detects and solves the cause of said variation in the electric potential before the total paralysis of the anaerobic digestion process occurs.
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    权利要求:
    Claims (4)
    [1]
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    1. Anaerobic digester monitoring procedure, which makes use of a device comprising a microbial combustion cell (1) linked to an anaerobic digester (2) through at least a first duct (3) and a second duct (4 ), a voltmeter (13) that determines the difference in electrical potential created inside the microbial combustion cell (1), and a control unit (14) that receives the measurements determined by the voltmeter (13), in the that the microbial combustion cell (1) in turn comprises:
    - a first pair of plates (5) separated from each other and made of an electric non-conductive material,
    - a cation exchange membrane (6) that divides the space between the plates of the first pair of plates (5) in a first compartment, corresponding to an anode (7) endowed with a microbial population analogous to that inside the digester ( 2), and a second compartment, corresponding to a cathode (8),
    - at least a third conduit (9) and a fourth conduit (10) linking the cathode (8) to a catholyte container (11), and
    - a second pair of plates (12) made of a conductive material linked to the plates of the first pair of plates (5),
    characterized in that it comprises the following phases:
    - entry into the anode (7) of a continuous flow comprising a mixture of effluent and biomass from inside the anaerobic digester (2) for oxidation,
    - entry into the cathode (8) of a catholyte from the tank (11) for its reduction,
    - measurement by the voltmeter (13) of the potential difference created inside the microbial combustion cell (1) due to oxidation and reduction reactions,
    - transmission of the potential difference measured by the voltmeter (13) to the control unit (14), and
    - exit of the anode (7) of the mixture of effluent and oxidized biomass through the
    second duct (9) for its return inside the anaerobic digester (2).
    [2]
    2. Anaerobic digester monitoring procedure according to revindication 1 characterized in that the control unit (14) emits a warning signal
    5 when it detects significant variations in the electrical potential determined by the voltmeter (13) inside the microbial combustion cell (1) to prevent the anaerobic digester from stopping (2).
    [3]
    3. Anaerobic digester monitoring procedure according to claim 1 characterized in that the voltmeter (13) makes the determination of the
    potential difference created inside the microbial combustion cell (1) in real time.
    [4]
    4. Anaerobic digester monitoring procedure according to claim 1 characterized in that the catholyte contained in the tank (11) comprises
    a solution of ferric cation that is introduced into the cathode (8) through the third conduit (9) to be reduced to ferrous cation.
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    同族专利:
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    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CA1332007C|1986-08-06|1994-09-13|Masahiro Fujii|Process for activated-sludge treatment of sewage or industrial waste water|
    EP1236688B8|1999-11-12|2005-01-05|Insertam S.L.|Biological purification plant for residual waters equipped with anaerobic digestors and purification process|
    DE10003620A1|2000-01-28|2001-08-02|Asat Ag Applied Science & Tech|Non-aqueous solution or suspension of 5-aminolevulinic acid, is useful in the treatment or diagnosis of tumor diseases or psoriasis by photodynamic therapy|
    CA2809494A1|2010-03-31|2011-10-06|Carbon Control Systems Inc.|Anaerobic digestion process monitoring device and method thereof|
    LU91846B1|2011-07-22|2013-01-23|Ct De Rech Public Gabriel Lippmann|Process for controlling and monitoring the production of biogas|
    法律状态:
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    PCT/ES2017/070152| WO2017158224A1|2016-03-18|2017-03-17|Method for monitoring anaerobic digesters|
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